KEGG   REACTION: R04280
Entry
R04280                      Reaction                               
Name
3-O-methylgallate:oxygen 4,5-oxidoreductase (decyclizing)
Definition
3-O-Methylgallate + Oxygen <=> 2-Pyrone-4,6-dicarboxylate + Methanol
Equation
Reaction class
RC00233  C00132_C05616
RC02694  C03671_C05616
Enzyme
1.13.11.8       1.13.11.-
Pathway
rn00627  Aminobenzoate degradation
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.13  Acting on single donors with incorporation of molecular oxygen (oxygenases)
   1.13.11  With incorporation of two atoms of oxygen
    1.13.11.8
     R04280  3-O-Methylgallate + Oxygen <=> 2-Pyrone-4,6-dicarboxylate + Methanol
    1.13.11.-
     R04280  3-O-Methylgallate + Oxygen <=> 2-Pyrone-4,6-dicarboxylate + Methanol
Orthology
K04100  protocatechuate 4,5-dioxygenase, alpha chain [EC:1.13.11.8]
K04101  protocatechuate 4,5-dioxygenase, beta chain [EC:1.13.11.8]
K15065  3-O-methylgallate 3,4-dioxygenase [EC:1.13.11.-]
Other DBs
RHEA: 31130

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